KINETIC STUDY OF REACTIONS OF SOME ORGANIC SULFUR COMPOUNDS WITH OH RADICALS

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Abstract

The reactions of OH radicals with the following organic sulfur compounds CH3SCH3, CH3SH, C2H5SH and C4H4S, have been studied by the discharge flow reactor technique associated to EPR and mass spectrometric detection. The products of the reactions of OH with CH3SH and C2H5SH have been studied mass spectrometrically. The results indicate that for both reactions the initial step would be equivalent to an H atom transfer.

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